I. Introduction
Millimeter waves up to THz are increasingly being used or foreseen in various applications such as 5G (backhaul), RFID tags to analyze the risks associated with aging structures, imaging for non-destructive control and security, automotive radars, radiometry,… Knowledge of the complex dielectric permittivity of materials is essential to achieve the specifications in the design of devices and systems at very high frequencies. Moreover, the study of the propagation and the interactions of waves with the environment also requires a detailed knowledge of these characteristics. Material characterization can be performed in a rectangular or coaxial waveguide, or in a cavity, where machined samples are inserted. Due to very small dimensions of the waveguides at millimeter waves and very small frequency bandwidth extraction in cavities, free space non-resonant techniques are preferred at very high frequencies [1].