Aging characteristics of polymeric materials by repeated surface flashovers in vacuum under microsecond pulse

Surface flashover characteristics of insulation materials in vacuum are key factors to determine the behavior of high voltage electrical equipment. Although the surface flashover in vacuum has been investigated for decades, the surface insulation properties of polymeric materials after repeated surface discharges have shown little attention by researchers. In order to investigate the aging characteristics of polymeric materials caused by repeated flashovers in vacuum, several typical materials were used to flashover by microsecond pulses. The flashover voltages were obtained for polytetrafluoroethylene, polymethylmethacrylate and polyamide for thousands of flashovers. The surface morphology of samples was observed after different numbers of flashovers. The trap parameter distribution was obtained by the isothermal surface potential decay method. To analyze the flashover voltage change with discharge times, the Weibull distribution was used to determine the conditioning and degradation effects in repeated discharge experiments. The results show that the morphology near the cathode triple junction and deep traps together affect the subsequent flashover voltage. The conditioning and degradation phenomena often coexist in the aging process of polymers and affect the surface insulation properties. This study could provide a reference for the type selection, design, and modification of insulation materials in vacuum.