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White LED is an emerging solid light source that potentially can replace the traditional light source.[1] The common way to make a white LED is by using phosphor to convert the UV LED emission into broadband white-light emission. [2]–[5] In this article, we used RBG phosphors and near-UV LED to fabricate white LED. Three materials were used as light converters, and a new Eu organometallic complex. Several optical measurements were taken before making use of the materials, such as photoluminescence excitation (PLE), emission spectra (PL), quantum efficiency and decay lifetime. Based on the optical measurement results, those three materials have good absorption in Near-UV range and also a good emission in visible. Thus, a novel mix of inorganic/organic luminescence materials produced a new white light phosphor. The white phosphor was applied onto the near-UV LED. As a result, a white emission LED is fabricated. Preliminary lifetime test indicated that the phosphor is robust showing no degradation over. a period of 100 hrs. This offers potential application in solid state white light source.