A Modified 2nd Order Kinetic Model by Including Temperature Effect and LODP of Oil-impregnated Paper under thermal degradation

The degree of polymerization is a useful technique to monitor insulation capabilities of oil impregnated paper. In present work, accelerated thermal ageing experiments have been conducted by taking Kraft and thermal upgraded papers along with two types of dielectric oil (mineral oil and vegetable oil) at different temperatures (90 °C, 110 °C and 130 °C). An improved 2nd order kinetic model has been developed based on experimental results which utilized to develop a relationship between temperature and final degree of polymerization. The proposed model can be used to analyze and monitor thermal deterioration of oil paper insulation at any temperature. Moreover, the proposed novel mathematical modelling can be employed to predict premature failure as well as end of life criteria of power transformers.