Non-Uniform Narrow Groove Plasmonic Nano-Gratings for SPR Sensing and Imaging

A surface plasmon resonance sensing and imaging platform based on plasmonic non-uniform nano-gratings with narrow groove (sub-10 nm) is presented. In these nanogratings, normally incident optical radiation is directly coupled to surface plasmons without the requirements of any other conventional surface plasmon coupling mechanisms such as prism-based or grating-based coupling. Theoretical analysis of practically realizable plasmonic non-uniform nano-gratings with rounded tops and slanted sidewalls is carried out to numerically to determine reflectance and differential reflectance signals when the localized refractive index of the medium around the gold layer present in these nano-gratings is changed. This change in the localized refractive index can occur due to the binding of biomolecules to the gold layer. Two kinds of plasmonic non-uniform nano-gratings are studied using finite difference time domain (FDTD) modelling: gold nano-gratings (GNGs) and gold-coated silicon nano-gratings (GSNGs). The plasmonic non-uniform nano-gratings being proposed, more specifically the GSNGs, can be easily fabricated with the presently existing nanofabrication and thin film deposition methods as opposed to uniform nano-gratings (with parallel sidewalls) that are very difficult to fabricate. The plasmonic non-uniform nano-gratings with narrow grooves eliminate the strict requirements on the angle of incidence for coupling of light into surface plasmons, which are needed in conventional prism-based coupling mechanisms. By employing FDTD calculations, we demonstrate that these plasmonic non-uniform nano-gratings provide very high differential reflectance amplitude values, which are indicative of high sensitivities of the SPR or SPRi sensors when the localized refractive index around the sensors is varied. Moreover, the sensors being proposed in this article provide a maximum sensitivity of localized refractive index sensing (i.e. surface sensitivity or
$\text{S}_{\mathrm {S}}$
) of 70 nm/nm with a figure of merit of the localized sensor (FOMS) of 1.5 nm
$^{-1}$
. This sensitivity of localized refractive index sensing is the highest reported thus far in comparison with previously reported plasmonic sensors. Moreover, these plasmonic non-uniform nano-grating based sensors exhibit significantly better performance when compared with conventional SPR or SPRi sensors based on the Kretschmann configuration.