Offline Multiobjective Optimization for Fast Charging and Reduced Degradation in Lithium-Ion Battery Cells Using Electrochemical Dynamics

The rapid charging of lithium ion battery cells while minimizing degradation is a key challenge in battery management. Offline optimal control frameworks employing physics-based models provide a first-principles approach to this problem that provides critical insights and benchmarks for real-time oriented online optimization algorithms. In this letter, we approach the optimal control problem of minimizing both charging time and degradation of a NMC battery using the single shooting optimization framework, employing a coupled electrochemical-thermal-aging model. The aging mechanism used captures growth of the SEI layer, solvent diffusion. The effectiveness of the single shooting method using a piecewise polynomial control and the low sensitivity of the method to chosen numerical parameters in the multi-objective problem is illustrated. The tradeoff between charging time and degradation is investigated numerically.