Comparative study of the viscoelasticity of parylene thin films for MEMS using Nano-DMA and Molecular Dynamics

We present a comparative study of the viscoelasticity of parylene C (PPXC) by using Nano-DMA (Dynamical Mechanical Analysis) and Molecular Dynamics (MD) simulations. By applying sinusoidal loading on PPXC films at different temperatures and frequencies, the complex modulus and glass transition temperature (T
_g
) of the PPXC were obtained. The predicted T
_g
determined from the temperature-dependent density change in the MD model is consistent with the results in our measurements and previous works. Furthermore, with Time-Temperature Superposition Principle (TTSP), we successfully determined the master curve of PPXC, for the first time, which is critical for the parylene reliability study of bio-MEMS devices.