Study of the absorption spectra of Fricke xylenol orange gel dosimeters

A systematic study of the absorption spectra of Fricke xylenol orange gel dosimeters has been performed, in the wavelength range from 300 nm to 700 nm. The spectrum of xylenol orange (without ferrous sulphate solution) has been achieved, in order to subtract its contribution from the absorption spectra of the irradiated Fricke xylenol orange gel dosimeters. The absorbance due to ferric ions chelated by xylenol orange has been studied for various irradiation doses. Two absorbance peaks are visible, mainly at low doses: the first peak increases with the dose more slowly than the second one. This effect can explain the apparent threshold dose that was frequently evidenced.