Cellulose chemical markers relationship with insulating paper post-mortem investigations

Oil soluble chemical markers such as methanol, ethanol and 2-furaldehyde for assessing the condition of insulating paper still present many challenges for an accurate interpretation in real transformers. Indeed, many conceptual parameters such as design (shell vs. core) or type of cooling are needed for a more accurate interpretation of the data. Moreover, similarly to water, the measured marker concentrations in oil are temperature-dependent, i.e. an existing partition phenomenon between the oil and the solid insulation modify the solubility of the markers, thus changing their apparent concentrations in the oil. Consequently, to follow the real trend of these species during the transformer's service life, it is crucial to correct their concentrations at a specific temperature, as is done for the water content. Knowing these facts and in order to calibrate a predictive model, Hydro-Québec decided to access equipment when dismantled, which enables a large amount of paper to be sampled from different sections of the windings. This allows for a more accurate representation of the transformer paper conditions in relation to transformer design. The paper condition obtained by measuring the degree of polymerization in accordance with the presence of chemical markers is a valuable process. We believe that it is possible to better understand the behavior of the paper insulation and to assess markers concentration thresholds using the oil analysis. This article discusses the recent experience in this field with specific cases.