Measurements of N2(A) by pulsed cavity ringdown spectroscopy in repetitively pulsed nanosecond discharges

We present here results from the measurements of metastable N
₂
(A) species in nanosecond repetitively pulsed (NRPP) discharge in N
₂
and air, obtained by using pulsed cavity ring-down spectroscopy (CRDS) at 770 nm. Despite the small plasma volume (1-10 mm
³
) and short lifetime of studied plasma species, CRDS enabled us to obtain spectra with spectral resolution down to 1 pm. The temporal variations of N
₂
(A) concentration in a nitrogen plasma were measured and absolute concentrations of N
₂
(A) in nitrogen and air plasmas were determined. These results were then used to validate a kinetic model, which already showed good agreement with the spatial and temporal evolution of other excited state species such as N
₂
(B), N
₂
(C), N
₂

⁺
(B), NO(A) and O(3p
⁵
P) measured using intensity calibrated emission spectroscopy.