Properties of MgB/sub 2/ films with very high transport critical current densities

Magnesium diboride, MgB/sub 2/, thin films are fabricated through two different kinds of process. One is an in-situ process by using electron beam deposition and the other is an ex-situ process by using the combination of pulsed laser deposition and heat treatment. The critical current density, J/sub c/, is investigated as a function of external magnetic field in the range of 0-7 T and/or temperatures ranging from 4.2 K to the critical temperature by using dc 4-probe transport method. The in-situ processed film shows very high J/sub c/, e.g., 7.1/spl times/10/sup 6/, 1.2/spl times/10/sup 6/, and 1.4/spl times/10/sup 5/ A/cm/sup 2/ in 0, 4, and 7 T (perpendicular fields), respectively. Angular dependence of J/sub c/ is much different between the two kinds of films. J/sub c/-angle (magnetic field) curves of the in-situ processed film show two peaks; one is around the field perpendicular to the film surface and the other is around the parallel field. On the contrary, the curves of the ex-situ processed film have only one peak around the parallel field. Microstructure analyses show that the in-situ film has columnar grains aligned perpendicular to the film surface and that the ex-situ one has granular grains with random orientations. These results indicate that the grain boundaries between columnar grains act as effective pinning centers and enhance J/sub c/ in the perpendicular fields.