Second-Order Adjoint Method for Quantum Optimal Control

We derive and implement a second-order adjoint method to compute exact gradients and Hessians for a prototypical quantum optimal control problem, that of solving for the minimal energy applied electric field that drives a molecule from a given initial state to a desired target state. For small to moderately sized systems, we demonstrate a vectorized GPU implementation of a second-order adjoint method that computes both Hessians and gradients with wall times only marginally more than those required to compute gradients via commonly used first-order adjoint methods. Pairing our secondorder adjoint method with a trust region optimizer (a type of Newton method), we show that it outperforms a first-order method, requiring significantly fewer iterations and wall time to find optimal controls for four molecular systems.