Understanding Multiple Stressors Which Degrade Antisoiling Coatings: Combined Effect of Rain, Abrasion, and UV Radiation

Antisoiling coatings (ASCs) are nano or microlayer coatings which reduce the settlement of dust on the surface of the PV module and are extensively investigated as a dust mitigation strategy. Since the coating is applied on the outer surface of the PV module, they are exposed to various environmental stressors, and the durability of these coatings is essential. Various studies have reported the effect of individual stressors that degrade ASCs. However, there are very few reports on the impact of the combination of stressors relevant to outdoor field conditions. In this article, we investigate the impact of the combination of the following stressors that degrade ASCs: 1) the combination of the impact of raindrops and acidic water, 2) the combination of UV radiation, the impact of raindrops, and acidic water, and 3) the combination of abrasion, UV radiation, the impact of raindrops and acidic water. The key takeaways from this study are 1) coating life reduced by 21× (average of all coatings) when exposed to the rainy season compared with those exposed to the nonrainy season. 2) All coated samples show lower coating life varying from 10× to 48× when exposed to the impact of raindrops with pH 7 water than those exposed to water immersion/water contact test with pH 7 water. This indicates that, during a rain event, the impact of raindrops hitting the coated surface causes more significant damage than water contact. This study shows that coatings A, B, C, and D are unreliable for long-term use in warm and humid climate zones, considering 25-year module lifetime. However, other chemistries of hydrophobic and hydrophilic solutions could be effective if they exhibit long-term reliability.