High-Performance Photodetector Based on Organic–Inorganic Perovskite CH3NH3PbI3/ZnO Heterostructure

In this letter, organic-inorganic hybrid perovskite CH₃NH₃PbI₃-based heterostructure photodetector is fabricated on fluorine-doped tin oxide (FTO) substrate. The perovskite CH₃NH₃PbI₃ and metal oxide ZnO are synthesized using the sol-gel chemical route. The synthesized hybrid perovskite CH₃NH₃PbI₃ has a tetragonal phase with a crystallite size of ~39.01 nm, whereas ZnO has a wurtzite hexagonal structure with a crystallite size of ~26.47 nm. The uniform distribution of particles is found in the thin film of CH₃NH₃PbI₃ and ZnO with an average particle size of ~50 and ~30 nm, respectively. An efficient photoluminescence band is observed at ~1.59 eV in CH₃NH₃PbI₃ thin film measured at ambient condition and excited with light of wavelength 405 nm. The heterostructure is formed between perovskite and ZnO, which also work as an efficient electron transport layer. The heterostructure is characterized using I-V and C-V measurements that confirm the formation of the barrier between CH₃NH₃PbI₃ and ZnO. The photoresponsivity of ~21.8 A/W is obtained at an applied bias voltage of -1 V under the illumination of light obtained from monochromator of wavelength ~436 nm and intensity ~190 μW/cm².