Indirect detection of DP for insulating paper based on methanol content in transformer oil by spectroscopic approach

In order to develop a novel detection method for the degree of polymerization (DP) of insulating papers, methanol was used as an indicator to explore the relationship between methanol concentration and DP in this paper. After extraction from oil, the methanol was oxidized and reacted with chromotropic acid to generate a purple-red compound. The spectral detection method was used to detect the concentration of methanol by absorbance, and then, the corresponding relationship between the concentration of methanol and the DP of insulating paper was established. Moreover, the detection methods based on furfural and methanol were compared. The results showed that methanol appeared during the initial aging period of the insulation paper, and the linear relationship between the methanol concentration and the DP of insulating paper was good. Compared with furfural, methanol was more sensitive to the change of DP in the early aging period, which proved that methanol could be used as a new type of indicator of insulating paper.