The influence of temperature and charge-discharge rate on open circuit voltage hysteresis of an LFP Li-ion battery

Open circuit voltage (OCV) is a crucial parameter in an equivalent circuit model (ECM). The path dependence of OCV is a distinctive characteristic of a Li-ion battery; this is known as OCV hysteresis. In this manuscript the influence of temperature and charge/discharge rate on OCV hysteresis has been identified. OCV hysteresis was found to be 13mV higher at 0°C while remaining unchanged at 45°C compared to the 25°C result. In general, OCV hysteresis was found to be less dependent on charge/discharge rate than temperature. The potential explanations of these results have been reported.