Synthesis of textured thermoelectric layered cobaltites by reactive templated grain growth

In order to apply layered cobaltites to thermoelectric (TE) devices, we need aligned ceramics to exploit their superior in-plane TE properties. Here, we report the preparation and characterization of c-axis aligned [Ca/sub 2/CoO/sub 3/]/sub 0.62/[CoO/sub 2/] (CCO) ceramics by the reactive templated grain growth (RTGG) method. As reactive templates, we synthesized platelike /spl beta/-Co(OH)/sub 2/ particles by a precipitation method. The template particles were mixed with a complementary reactant, CaCO/sub 3/, and aligned by a tape-casting. Upon heat treatment, they reacted to form a CCO ceramic with almost perfectly c-alignment (Lotgering's orientation degree, f > 0.99). The highly textured ceramic shows significantly large in-plane electrical conductivity (/spl sigma//sub ab/): i.e., the value of /spl sigma//sub ab/ was 2.61 /spl times/ 10/sup 4/ S/m at 1060 K, where the value is around 60 % of that of a single crystal. We conclude that the RTGG method must be an effective and versatile technique for the preparation of large-sized TE materials with high TE performances.