CHD/sub 2/OH optically pumped by a waveguide CO/sub 2/ laser: new far-infrared laser lines from the CD/sub 2/ wagging vibrational mode

For the first time, a wide tunability waveguide CO/sub 2/ laser was used to pump the CHD/sub 2/OH molecule for the generation of new FIR laser lines with a large offset. Optoacoustic signals associated with the infrared absorbing transitions of the CD/sub 2/ wagging vibrational mode served as a guide for finding new laser lines. All lines were characterized in wavelength, relative polarization, intensity, optimum pressure of operation, and precise offset measurements.