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Synthesis of molecular dodecanuclear carbon-centered rhenium cluster Re12CS17 and its conducting properties

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7 Author(s)
Fedorov, V.E. ; Nikolaev Inst. of Inorg. Chem., Russian Acad. of Sci., Novosibirsk, Russia ; Gabuda, S.P. ; Kozlova, S.G. ; Gayfulin, I.M.
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The unique dodecanuclear cluster compound Re12CS17 was prepared and studied by X-ray, complex impedance method and density functional theory (DFT). The compound possesses semiconducting properties. Computer simulations showed that the Re and S atoms at the external borders of the neighboring molecules Re12CS17 can form strong intermolecular bonds Re ... S, similar to the intermolecular bonds of Mo ... S cuboctahedron Mo6S8 molecules in the Chevrel phases.

Published in:

MIPRO, 2011 Proceedings of the 34th International Convention

Date of Conference:

23-27 May 2011