Kinetics of High-Temperature Processes

Cover Image Copyright Year: 2003
Author(s): William D. Kingery
Publisher: MIT Press
Content Type : Books & eBooks
Topics: General Topics for Engineers
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Abstract

A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems.

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      Front Matter

      Page(s): i - 7
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Half Title, Technology Press Books in Science and Engineering, Title, Copyright, Endicott House Conference, Endicott House Conference Participants, Conference Committee, Participants and Contributors, Preface, Contents, Introduction View full abstract»

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      Imperfections and Diffusion in Nonmetals

      Page(s): 9
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

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      Certain Aspects of Diffusion and Conduction in Alkali Halides

      Page(s): 11 - 13
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Work, Discussion, References, Acknowledgement View full abstract»

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      Defect Reactions in TiO2

      Page(s): 13 - 19
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Computation of the Equilibrium Constant, Discussion, References, Acknowledgement View full abstract»

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      Contribution to the Study of Order in Spineis at High Temperatures

      Page(s): 19 - 21
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: References View full abstract»

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      Imperfection Interactions in Aluminum Oxide

      Page(s): 21 - 30
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Dislocations, Lattice Vacancies and Impurities, Impurities along Dislocations, References, Acknowledgments View full abstract»

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      Polygonization of Sapphire

      Page(s): 30 - 37
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Polygonization of Sapphire, Discussion, Law of Polygon Growth, Summary and Conclusions, References, Acknowledgments View full abstract»

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      Diffusion in Oxides

      Page(s): 37 - 44
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Diffusion in Stoichiometric Systems, Diffusion in Nonstoichiometrics Oxide, Summary, References, Acknowledgment View full abstract»

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      Oxygen Ion Self-Diffusion in Uranium Dioxide

      Page(s): 44 - 49
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Work, Results and Discussion, References, Acknowledgments View full abstract»

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      Diffusion of Oxygen in Rare-Earth Oxides

      Page(s): 50 - 57
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Praseodymium Oxide, Terbium Oxides, References, Acknowledgment View full abstract»

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      Measurements of Diffusion in the System TiO2-SnO2

      Page(s): 58 - 61
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Procedure, Calculations and Results, Discussion, Conclusions, References, Acknowledgments View full abstract»

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      The Mechanism for Atom Motion in Graphite Crystals

      Page(s): 61 - 66
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Graphite, Diffusion Measurements, Theoretical Work, Irradiation Effects, Quenching, The Mechanism for Self-Difussion, References, Acknowledgement View full abstract»

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      Discusssion: Chapters 1-10

      Page(s): 66 - 76
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: References View full abstract»

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      Diffusion in Liquids and Liquid-Solid Reactions

      Page(s): 77
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

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      Diffusion in Molten Silfides

      Page(s): 79 - 80
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Measurements, References, Acknowledgement View full abstract»

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      Diffusion in Liquid Silicates

      Page(s): 80 - 85
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Work, Results, Discussion Results, References View full abstract»

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      Corrosion of Refractories by Liquid Slags and Glasses

      Page(s): 85 - 92
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Basic for Experimental Evaluation, Experimental Arrangements, Model Systems, Conclusions, References, Acknowledgement View full abstract»

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      The Kenetics of Solution of Tungsten Carbide in Molten Cobalt

      Page(s): 92 - 97
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Previous Work, Experimental Method, Experimental Results, Discussion of Results, Summary, References, Acknowledgements View full abstract»

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      Discusssion: Chapters 11-14

      Page(s): 97 - 99
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Nucleation and Grain Growth

      Page(s): 101
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Contribution to Nucleation Theory from Kinetic Studies in Semiconductors

      Page(s): 103 - 109
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: General Nucleation Theory, Precipitation Studies in Semiconductors, References, Acknowledgement View full abstract»

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      Grain Growths in Ceramics

      Page(s): 109 - 116
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: The Geometry of Grain Growth, Geometry of Grain Growth in Ceramics, Atom Movements in Boundary Migration, Preferred Orientations from Grain Growth, Grain Shape, Presence of a Liquid Phase, References, Acknowledgements View full abstract»

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      Crystal Growth During Calcination

      Page(s): 116 - 120
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Method of Measuring Crystal Size, References View full abstract»

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      Nucleation and Nuclei Growth in Sintered Alumina

      Page(s): 120 - 127
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Theory of Nucleation and Nuclei Growth, Nucleation of Sintered Alumina, Rate of Nuclei Growth, Summary, References, Acknowledgement View full abstract»

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      Kinetics of Solidification from Nonmetallic Liquids

      Page(s): 127 - 135
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, The Relationship Between Heat Flow and Material Transport During Solidification, Theories of Growth Kinetics, Experimental Observations, Remarks, Summary, Appendix, References, Acknowledgement View full abstract»

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      Discusssion: Chapters 15-19

      Page(s): 135 - 143
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: References View full abstract»

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      Sintering and Vitrification

      Page(s): 145
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Diffusion Sintering in the Solid State

      Page(s): 147 - 163
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Phenomenology, Vacancy Sources and Sinks, Geometric Changes, Second Order Effects, Results and Discussion, Termination of the Initial Stage of Sintering, Geometric Considerations: Transition Stage, Forming Pressure, Grain Growth, Shrinkage Control, Closed-Pore Shrinkage, General Variables, References View full abstract»

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      Shintering Mechanisms of Aluminum Oxide

      Page(s): 163 - 172
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental, Discussion, Conclusions, References, Acknowledgements View full abstract»

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      Role of Grain Boundaries in Sintering

      Page(s): 172 - 178
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Development Theory, Experiments with Wires and Foils, Sintering Experiments, Conclusion, References View full abstract»

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      The Relationship Between Free Energy and Kinetics in Sintering Process

      Page(s): 179 - 186
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Some Introductory Theoretical Remarks, Experimental, Discussion of Results, Summary, References View full abstract»

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      Sintering in the Presence of a Liquid Phase

      Page(s): 187 - 194
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Theoretical Work, Experimental Work, Summary, References View full abstract»

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      Discusssion: Chapters 20-24

      Page(s): 194 - 201
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Phase Transformations

      Page(s): 203
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

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      Order-Disorder Theory: Its Application to Binary Alloys and to the Kinetics of Diffusionless Transitions in Solids

      Page(s): 205 - 216
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction Comments, The Quasi-Chemical Approximation, Some Mathematical Properties of the function βj, Extension of Theory to the Rate of the Phase Transformations in Solids, References, Acknowledgements View full abstract»

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      Structural Control in Some Mineral Reactions

      Page(s): 217 - 222
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Polymorphic Transformations, Solid-State Reactions, Structural Evidence on the Nature of Solid-State Reactions, Transformation of Serpentine to Forsterite, Transformation of Chlorite to Forsterite or Olivine, Transformation of Kaolinite to Mullite and the Intermediate Phases, Transformation of Cronstedtite to a Spinel Phase and to Haematite, Oriented Transformations in Iron Oxides and Hydroxides, The Alumina Hydroxides and Oxides, Discussion, References View full abstract»

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      Kinetics of the Transformation of Quartz

      Page(s): 222 - 227
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Estimation of Cristobalite and Tridymite by Differential Thermal Analysis, Current Investigations, Results with Madagascar Quartz, Derivation of K1 and K2, Results with Brazilian Quartz, Brazilian versus Madagascar Quartz, General Conclusions, References View full abstract»

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      The Anomalous Inversion in Cristobalite

      Page(s): 228 - 238
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Characterization of the Anomalous Inversion, The Inversion Temperature and the Kinetics of Formation of Perfect Cristobalite, Hysteresis and the Kinetics of the Inversion, Conclusions, References View full abstract»

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      Discusssion: Chapters 25-28

      Page(s): 239 - 240
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Solid-Solid Reactions

      Page(s): 241
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Solid Reactions in Ferrites

      Page(s): 243 - 254
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Type I Ferrite Reaction, Type II Ferrite Reaction, Type III Ferrite Reaction, Type IV Ferrite Reaction, Type V Ferrite Reaction, Conclusion, References View full abstract»

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      Solid Reactions Forming BaTiO3

      Page(s): 255 - 264
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Experimental Work, Summary, References, Acknowledgements View full abstract»

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      Kinetics in Graphitization

      Page(s): 264 - 270
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Polymerization, Chars, Turbostratics Carbons, Polycrystalline Graphite, References View full abstract»

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      Discusssion: Chapters 29-31

      Page(s): 271 - 274
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Solid-Gas Reactions

      Page(s): 275
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Metal-Gas Reactions

      Page(s): 277 - 281
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Dissolution and Diffusion of Gases, Formation of Volatile Products, Formation of Liquid Products, Formation of Solid Products, References, Acknowledgement View full abstract»

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      Investigations on the Oxidation of Metals as a Tool for the Exploration of the Movement of Ions in Solid Oxides

      Page(s): 282 - 293
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Diffusion and Transport Processes in Oxide Layers, Oxide-Layer Formation at High Temperature, Factors Affecting Oxidation Rates at High Temperatures, Oxide-Layer Formation at Medium and Low Temperatures, Chemisorption and Space-Charge Boundary Layers in Oxides, Transport Processes in Space-Charge Boundary Layers, Some Applications to Problems of Ceramic Chemistry, References, Acknowledgement View full abstract»

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      Kinetics of the Thermal Decomposition of Some Minerals

      Page(s): 294 - 301
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Introduction, Carbonate Decomposition, Decomposition of Hydrated Minerals, References, Acknowledgements View full abstract»

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      The Thermal Decomposition (Dehydroxylation) of Clays

      Page(s): 301 - 308
      Copyright Year: 2003

      MIT Press eBook Chapters

      This chapter contains sections titled: Previous Investigations, Influence of Crucible Type, Clay Mass, and Compaction of the Clay on the Velocity of Decomposition, The Effect of Water-Vapor Pressure on the Decomposition Rate, The Nature of the Rehydration Reaction, Relation Between Rehydration and Water-Vapor Pressure, References View full abstract»

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      Discusssion: Chapters 32-35

      Page(s): 308 - 313
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Author Index

      Page(s): 315 - 319
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»

    • Full text access may be available. Click article title to sign in or learn about subscription options.

      Subject Index

      Page(s): 321 - 326
      Copyright Year: 2003

      MIT Press eBook Chapters

      A symposium on condensed-phase processes at high temperatures, particularly in nonmetal systems, which presents a record of recent efforts to understand the field and apply this understanding to complex systems. View full abstract»