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Synthesis of molecular dodecanuclear carbon-centered rhenium cluster Re12CS17 and its conducting properties

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7 Author(s)
V. E. Fedorov ; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Novosibirsk, 630090, Russia ; S. P. Gabuda ; S. G. Kozlova ; I. M. Gayfulin
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The unique dodecanuclear cluster compound Re12CS17 was prepared and studied by X-ray, complex impedance method and density functional theory (DFT). The compound possesses semiconducting properties. Computer simulations showed that the Re and S atoms at the external borders of the neighboring molecules Re12CS17 can form strong intermolecular bonds Re ... S, similar to the intermolecular bonds of Mo ... S cuboctahedron Mo6S8 molecules in the Chevrel phases.

Published in:

MIPRO, 2011 Proceedings of the 34th International Convention

Date of Conference:

23-27 May 2011