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2,4-Dichlorophenol Degradation by Heterogeneous Fenton Like Reaction Using carbon-Fe Catalysts

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5 Author(s)
Yang Yinchun ; Dept. of Environ. Sci. & Eng., Chengdu Univ. of Inf. Technol., Chengdu, China ; He Liping ; Xu Chenghua ; Ye Zhixiang
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Catalytic degradation of simulated 2,4-dichlorophenol wastewater are investigated by using self-synthesized Fe/activated carbon (AC) catalysts and hydrogen peroxide oxidation agent. Effects of the most relevant operating conditions(pH, catalysts concentration, 2,4-dichlorophenol concentration, H2O2 concentration and reaction temperature) were discussed. The results indicate that the degradation rate of 2,4-dichlorophenol (400 mg/L) reach 79.9% in the presence of Fe/AC(2g/L) and hydrogen peroxide (1%) at pH = 3 after 180 minutes under normal temperature and atmospheric pressure. Kinetic studies of the catalytic reaction showed that the degradation reaction of 2,4-dichlorophenol nearly follows the first-order reaction, the reaction constant and activity energy are 0.00626 mm-1 and 66.50 kJ/mol at 30degC, respectively.

Published in:

Bioinformatics and Biomedical Engineering , 2009. ICBBE 2009. 3rd International Conference on

Date of Conference:

11-13 June 2009