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We propose a predictive model of structural changes in elementary sub graphs of social network based on Mixture of Markov Chains. The model is trained and verified on a dataset from a large corporate social network analyzed in short, one day-long time windows, and reveals distinctive patterns of evolution of connections on the level of local network topology. We argue that the network investigated in such short timescales is highly dynamic and therefore immune to classic methods of link prediction and structural analysis, and show that in the case of complex networks, the dynamic sub graph mining may lead to better prediction accuracy. The experiments were carried out on the logs from the Wroclaw University of Technology mail server.