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Low temperature processing solid-state dye sensitized solar cells

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6 Author(s)
Jiang, C.Y. ; Institute of Materials Research and Engineering, A*STAR, 3 Research Link, Singapore 117602 ; Koh, W.L. ; Leung, M.Y. ; Chiam, S.Y.
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Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.3693399 

A study on low temperature processed solid state dye sensitized solar cell (LT-SDSC) is reported. The LT-SDSC uses a photoelectrode with a mesoporous TiO2 (mp-TiO2) film fabricated from a binder-free nanoparticle-TiO2 paste at room temperature, and a blocking layer of an amorphous TiO2 thin film deposited by atomic layer deposition (ALD) at 150 °C. A power conversion efficiency of 1.30% is obtained from the LT-SDSC with 0.9 μm mp-TiO2 layer and 20 nm ALD-TiO2 blocking layer, in cooperating with organic indoline dyes and a hole conductor, 2,2′,7,7′-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9′-spirobifluorene (Spiro-OMeTAD). The lower electron conductivity of the low-temperature-processed mp-TiO2 film and the amorphous blocking layer is equilibrated by using smaller thicknesses of the films. Ways to further boost the LT-SDSC performance are proposed. These LT-SDSC are potentially compatible with low cost plastic substrates and show promising manufacturing potential for low cost flexible SDSCs.

Published in:

Applied Physics Letters  (Volume:100 ,  Issue: 11 )

Date of Publication:

Mar 2012

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