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Dependence of surface free energy on molecular orientation in polymer films

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4 Author(s)
Stachewicz, Urszula ; Nanoforce Technology Ltd., Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom ; Li, Shuangwu ; Bilotti, Emiliano ; Barber, Asa H.

Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.3691186 

Surface free energy of mechanically drawn polycarbonate films was determined using contact angle measurements and shown to increase with orientation. The increase in polymer film surface free energy was attributed to increased polymer chain packing during orientation, supported by film density measurements, which provides enhanced intermolecular interactions. Surface free energy can therefore be increased by, or used to predict, polymer orientation.

Published in:
Applied Physics Letters  (Volume:100 ,  Issue: 9 )

Date of Publication: Feb 2012

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