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In order to select proper ammunition to attack a certain target, we proposed a new method for ammunition target matching sequencing based on rough set and weighted TOPSIS. After depicting the mechanism of ammunition damage and target anti-damage, the authors constructed the ammunition target matching index system. Rough set theory was applied to reduce index and decide the weights of key index. The technique for order preference by similarity to ideal solution (TOPSIS) is applied to decide ammunition target integrated matching sequencing. This new method could help commands to make proper decision on optimal firepower assignment.