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In view of the advantage of combination of agent and web service, introducing agent and web service into distributed data mining, a multi-layer distributed data mining model based on intelligent agent and web service technologies is presented to overcome difficulties of the traditional distributed application technologies such as distribution, heterogeneity, autonomy. This model describes the general framework, the distribution of Agents, the function of agents and web service component. This framework is applied to data mining for gas fields with MAS to improve performance and flexibility of system. Finally, The research results has greatly increased gas-field production safety management level and gained good economic and the social benefit.