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Quantum mobile communication is one of the hot-topics in the field of information, but entanglement signaling of quantum mobile communication radio interface transmission scheme is still a gap till now. Hence, this article firstly raises the concept of the Quantum Entanglement Signaling (QES) and frame structure of QES based on the conception. For the Quantum Mobile Terminal (QMT), this article studies the location registration, location update, and signaling processing and transmission scheme during the routing process. Then, the capacity between the Quantum Mobile Terminal (QMT) and the Quantum Mobile Base (QMB) in two-way communication is discussed. The results of the study indicate that quantum entanglement signaling transmission scheme and the capacity of radio interface proposed in this article can meet the needs of quantum mobile network for signaling transmission in the future.