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The integral equation (IE) method is commonly utilized to model time-harmonic electromagnetic (EM) problems. One of the greatest challenges in its applications arises in the solution of the resulting ill-conditioned matrix equation. We introduce a new domain decomposition method (DDM) for the IE solution of EM wave scattering from non-penetrable objects. The proposed method is a non-overlapping/non-conformal DDM and it provides a computationally efficient and effective preconditioner for the IE matrix equations. Moreover, the proposed approach is very suitable for dealing with multi-scale electromagnetic problems since each sub-domain has its own characteristics length and will be meshed independently. Furthermore, for each sub-domain, we are free to choose the most effective IE sub-domain solver based on its local geometrical features and electromagnetic characteristics. Additionally, the multilevel fast multi-pole algorithm (MLFMA) is utilized to accelerate the computations of couplings between sub-domains. Numerical results demonstrate that the proposed method yields rapid convergence in the outer Krylov iterative solution process. Finally, simulations of several large-scale examples testify to the effectiveness and robustness of the proposed IE based DDM.