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With a thermo gravimetric analysis apparatus combustion characteristics experiments of sawdust, corn straw and mixtures of them were done at 10,20,40°C/min heating rate. The combustion activation energy was acquired by kinetics analysis. The experiment results show that the ignition characteristic and synthesis combustion of corn straw are better than sawdust. The mixture of corn straw and sawdust was easier than each one of them by compression molding.