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The paper mainly discussed the cooperation technology and communication mechanism and KQML language of Multi-Agent system based on the study of the concept, characteristics and system structure, also we have done helpful investigations and attempts about the practicality of Agent technology. Through introducing the Agent technology, and using the learners' records of their database to analyze the students' learning, students Agent, P. E. teachers Agent, P.E. management Agent and their mutual interactions, a remote P.E. teaching system based on multi-agent was developed, which can provide intelligence services for students' learners, teaching students in accordance with aptitude and realize the intelligence of remote sports teaching.