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The profit allocation among normal supply chain is normally based on the Shapely Value. This paper introduces the environmental performance in profit allocation among the normal supply chain. Then use the multi-level fuzzy comprehensive evaluation method to quantize the environmental performance impact on profit allocation, and get the program for the profit allocation among green supply chain based on the optimized Shapely Value whose key is how to quantize the environmental performance of enterprises to quantify. The results show that the green supply chain can achieve the greater competitive advantage, it also can bring more benefits for enterprises, integrate the appropriate resources and optimize the interests of node distribution business by introducing the environmental factors.