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CSE-2010 is the next event in a series of highly successful International Conferences on Computational Science and Engineering, held mainly as the International Workshop on High Performance Scientific and Engineering Computing for 10 editions, mostly in conjunction with International Conference on Parallel Processing (ICPP), as COATA-98 (Orlando, USA, July 1998), HPSEC-99 (Fukushima, Japan, September 1999), HPSEC-00 (Toronto, Canada, August 2000), HPSEC-01 (Valencia, Spain, September 2001), HPSEC-02 (Vancouver, Canada, August 2002), HPSEC-03 (Kaohsing, Taiwan, October 2003), HPSEC-04 (Montreal, Canada, August 2004), HPCSE-04 with WCC-04 (Toulouse, France, August 2004), HPSEC-05 (Oslo, Norway, June 2005), and HPSEC-06 (Columbus, USA, August 2006). The previous CSE-08 and CSE-09 were held in Sao Paulo, Brazil, July 16-18, 2008 and Vancouver, Canada, August 29-31, 2009. Workshops play a key role in the success of a conference and the WMSC-2010 focuses upon a cornerstone of workflow in service and cloud computing environments. The workshop had 26 papers submitted from a truly international set of authors. Of these 26 papers a final group of 14 papers were selected for oral presentation. Each of these had 2 reviews that were undertaken by an internationally recognized collection of workflow and service computing experts.