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Surface plasmonic controllable enhanced emission from the intrachain and interchain excitons of a conjugated polymer

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5 Author(s)
Cho, Kwan Hyun ; Department of Electrical Engineering, KAIST, Daejeon 305–701, Republic of Korea ; Ahn, Sung Il ; Seong Min Lee ; Choi, Chung Sock
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We demonstrate selectively enhanced emission by controlling the intrachain and interchain excitons of a conjugated polymer through adjusting surface plasmons. Enhanced light emission from the intrachain excitons was observed by coupling the localized surface plasmon resonance with the intrachain band of the conjugated polymer using Ag nanoparticles. Light emission from the interchain excitons was enhanced by exploiting both the increased strength of the interchain dipole due to the image dipole and the coupling between excitons and surface plasmon polaritons (SPPs). As the Ag nanostructures become complete films, light emission from the interchain excitons increased.

Published in:

Applied Physics Letters  (Volume:97 ,  Issue: 19 )

Date of Publication:

Nov 2010

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