Improved performance of small molecule bulk heterojunction (BHJ) organic solar cells based on 4,7-bis(2-triphenylamino-3-dodecyl-thiophene-5-yl)-benzo[c][1,2,5]thiadiazole (TTBTT)/PC71BM (1:3, w/w) blend has been obtained by using 1,8-octanedithiol (ODT) as a processing additive. Based on the analysis of absorption spectrum, charge transport, and film morphology, the 30% enhancement in power conversion efficiency (PCE) via 1% ODT addition is attributed to aggregated domain formation, enhanced absorption, improved hole mobility, and more balanced charge transport. Finally, a PCE as high as 2.86% was achieved, which is among the top reported for solution-processed small molecule BHJ organic solar cells.
Published in:
Applied Physics Letters
(Volume:97
,
Issue:
13
)
Date of Publication:
Sep 2010
- Page(s):
-
133302
-
133302-3
- ISSN :
-
0003-6951
- Digital Object Identifier :
-
10.1063/1.3491268
- Product Type:
-
Journals & Magazines
- Date of Current Version :
-
30 September 2010
- Issue Date :
-
Sep 2010