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The paper put forward an application architecture for wireless sensor network based on Semantic P2P. Integrating the merits of RFID technology, the paper proposed a new SCM monitoring platform based on the wireless sensor networks and RFID. The architecture used Semantic P2P technology to solve the information overload communications bottlenecks, facilitate the deployment of sensor nodes and make sensor networks easy to expand. The paper used the Ontology technology to make the semantic information communicate in SCM successfully and efficiently.