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The ability to respond to emergency is one of the significant indicators to measure the level of enterprise administration. Enterprise emergency response capability assessment can be the elements of emergency management and provide credible warrant for emergency preparative. It is of great significance to establish a set of evaluation system to identify the achievements and deficiency in the enterprise emergence management work. This paper presents a grey AHP approach to the enterprise emergency response capability evaluation. The weight of each index is derived by AHP and the weight among its indicators is derived by grey theory. Finally, the simulation example is presented.