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Radiotracer techniques were used to study the sorption of sulfur vapor by silicone and epoxy polymers and to obtain information on the diffusion of sulfur in these materials. Sulfur was found to enter silicone polymers solely by a physical solution process which obeys Henry's law. The heat of solution is large (−0.43 eV) and at room temperature the solubility coefficient is at least five orders of magnitude greater than for many fully gaseous solutes, a result which fits an empirical rule relating the solubility coefficient of a given solute to its boiling point. Sorption of sulfur by a flexibilized anhydride-cured diglycidyletherbisphenol-A (DGEBA) epoxy is somewhat more complicated and appears to involve a double process of physical solution and chemical reaction. The rapid diffusion of sulfur in silicone rubber necessitated measurements of the diffusion coefficient D by a vacuum desorption technique. The activation energy Q and pre-exponential constant D
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