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[Pt]Polypyrrole: A New Organic Electrode Material

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3 Author(s)
Diaz, A. ; IBM Research Division laboratory, 5600 Cottle Road, San Jose, California 95193, USA ; Vallejo, J.M.Vasquez ; Duran, A.Martinez

Films of BF4-doped polypyrrole grown on platinum, hereafter termed [Pt]polypyrrole, were used as electrodes in a series of reactions. These organic electrodes are found to be quite stable and nonporous; they generally do not perturb the redox reactions of dissolved species and they display rapid surface-substrate electron-transfer kinetics. The polypyrrole films are sensitive to the presence of Lewis bases in solution, which apparently act as nucleophiles, leading to degradation of the electrode properties.

Note: The Institute of Electrical and Electronics Engineers, Incorporated is distributing this Article with permission of the International Business Machines Corporation (IBM) who is the exclusive owner. The recipient of this Article may not assign, sublicense, lease, rent or otherwise transfer, reproduce, prepare derivative works, publicly display or perform, or distribute the Article.  

Published in:

IBM Journal of Research and Development  (Volume:25 ,  Issue: 1 )

Date of Publication:

Jan. 1981

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