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Magic Angle Spinning NMR of Conducting Polymers

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3 Author(s)
T. C. Clarke ; IBM Research Division, 5600 Cottle Road, San Jose, California 95193, USA ; J. C. Scott ; G. B. Street

Because of their typically intractable nature, conducting polymers as a class of materials have proved particularly difficult to characterize by the conventional techniques of polymer analysis. We present here examples of the application of a powerful new tool, cross-polarization magic angle spinning (CPMAS) 13C NMR spectroscopy, to the investigation of the structure and reactions of the conducting polymers polyacetylene and polypyrrole.

Note: The Institute of Electrical and Electronics Engineers, Incorporated is distributing this Article with permission of the International Business Machines Corporation (IBM) who is the exclusive owner. The recipient of this Article may not assign, sublicense, lease, rent or otherwise transfer, reproduce, prepare derivative works, publicly display or perform, or distribute the Article.  

Published in:

IBM Journal of Research and Development  (Volume:27 ,  Issue: 4 )