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Appropriate methods are helpful to measure risk. The risk is objective in acquisitions. It resources from subjective risk, morality risk, information asymmetry risk, law risk, system risk, policy risk and market risk during the process of mergers and acquisitions decision-making. In the different stages of decision-making, the emphases of risks are different Index of measuring risks can be established by industrial experts. The case demonstrates that genetic algorithm and BP neural network are good tools to measure the risks.