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with the development of computer and network, new control methods appear in industrial control system. And more intelligent and roboticized agent technology also appears after artificial intelligence (AI). Agent technology is farther development of AI. Wind and solar energy complementary power generation is a novel and promising power system, but because of randomicity and complexity of the climate, it makes wind and solar complementary power generation system a complicated system. In this paper, we first introduce advanced agent technology into wind and solar energy complementary power generation system, Then we establish the multi-agent decision-making model of wind and solar energy complementary power generation MADMWSCPS. In the MADMWSCPS, according to its function, the whole system is divided into several agent modules and each agent module is divided into some detailed agents. At last, we realize a decision-making process by the flexible collaboration and communication of these agents. The scheme can be applied into sea-island, remote region, unmanned operation' wind-solar energy complementary power generation system, it can enhance power system' intelligence and reliability.