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The environment pollution is becoming more and more important with the enterprise development. In this paper, the game theory is used to analyze the problem of enterprise environment pollution. Two aspects have been analyzed, between enterprise and enterprise, and between enterprise and government. For the enterprise and enterprise, some classic models have been used, such as prison dilemma, pig's payoffs, chicken game and tragedy of commons. For the enterprise and government, the static game of complete information model has been set up and the solution has been fond. In the end, directions of the future research have been proposed.