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Mobile business is a promising industry created by the emergence of wireless date networks. The users could use mobile terminals to transmit data and conduct business activities. The 4G self-organization mobile business network is a sort of business network in which the clients and the services or goods providers, both of whom move freely, could organize a self-organized network rapidly especially without infrastructure in emergency situation or in the case of requiring high privacy. It isolates from public network. This paper proposes a model of 4G self-organization mobile business network and then displays the trait of it.