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Bismuth Substitution in Yttrium Iron Aluminum Garnets

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4 Author(s)
Geller, S. ; Bell Telephone Laboratories, Incorporated, Murray Hill, New Jersey ; Williams, H.J. ; Sherwood, R.C. ; Espinosa, G.P.

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Magnetic, crystallographic, and preparative data are reported on the system {Y2.75Bi0.25} Fe5-xAlxO12 for values of x to 1.50. For large x there appear to be differences in 0°K magnetic moment between this system and the straight yttrium analog, which imply that the replacement of Y3+ by the larger Bi3+ ions favors occupation of the tetrahedral sites by the smaller Al3+ ions. The replacement of Y3+ by Bi3+ ions leads to the reduction of the preparation temperature of aluminum substituted iron garnets by about 350°C.

Published in:

Journal of Applied Physics  (Volume:35 ,  Issue: 6 )

Date of Publication:

Jun 1964

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