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Nuclear Magnetic Resonance Study of the Niobium‐Nitrogen System NbNx

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3 Author(s)
Bennett, Robert A. ; Department of Physics, Wayne State University, Detroit, Michigan 48202 ; Hooper, H.O. ; Roy, U.

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Nuclear magnetic resonance has been employed to identify the phases of the system NbNx in several samples of niobium nitride. The ϵ phase has been identified by a characteristic second‐order quadrupolar broadened central transition with two sets of satellite lines also being observed. The quadrupole coupling constant has been determined for the ϵ phase (e2qQ/h=10.6±0.1 MHz) and for the δ phase (e2qQ/h=4.3±0.4 MHz). The relative amounts of the phases present in a sample were also determined in two samples.

Published in:

Journal of Applied Physics  (Volume:40 ,  Issue: 6 )