By Topic

Evaluation of ionic mobility and transference number in a polymeric solid electrolyte by isothermal transient ionic current method

Sign In

Cookies must be enabled to login.After enabling cookies , please use refresh or reload or ctrl+f5 on the browser for the login options.

Formats Non-Member Member
$31 $31
Learn how you can qualify for the best price for this item!
Become an IEEE Member or Subscribe to
IEEE Xplore for exclusive pricing!
close button

puzzle piece

IEEE membership options for an individual and IEEE Xplore subscriptions for an organization offer the most affordable access to essential journal articles, conference papers, standards, eBooks, and eLearning courses.

Learn more about:

IEEE membership

IEEE Xplore subscriptions

4 Author(s)
Watanabe, M. ; Department of Chemistry, Sophia University, 7‐1 Kioi‐cho, Chiyoda‐ku, Tokyo 102, Japan ; Rikukawa, M. ; Sanui, K. ; Ogata, N.

Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.336191 

We proposed a new method for evaluating mobilities of both Li+ and SCN- ions in a polymeric solid electrolyte formed by poly (ethylene succinate) and LiSCN. The method is based on the isothermal transient ionic current (ITIC) technique by using an ion‐blocking platinum electrode and an ion‐reversible lithium electrode. The differences of the ITIC profiles, depending on the kind of the electrodes, provided both mobilities of Li+ and SCN- ions, and their assignment. The mobilities of Li+ and SCN- ions at 90 °C were 1.3–4.2×10-6 cm2 V-1 s-1 and 5.3–10.7×10-8 cm2 V-1 s-1, respectively. The transference number of Li+ ions was 0.92–0.99.

Published in:

Journal of Applied Physics  (Volume:58 ,  Issue: 2 )