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Effects of surface step and substrate temperature on nanostructure of L10FePt nanoparticles

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6 Author(s)
Sato, Kazuhisa ; The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan ; Kajiwara, Takenori ; Fujiyoshi, Masaru ; Ishimaru, Manabu
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The variation of the particle size, particle density, and its relation to the hard magnetic properties of FePt nanoparticles with respect to substrate temperatures and substrate surface morphologies has been investigated. On geometrically flat surfaces, densely dispersed FePt nanoparticles with a particle density of 1012cm-2 were obtained at a substrate temperature below 573 K, while substrate temperatures between 623 and 823 K are necessary for obtaining well-oriented and well-isolated L10FePt nanoparticles with large coercivity. Isolated particles fabricated above 573 K did not coalesce largely upon annealing at 873 K, which can be attributed to the “anchoring effect” of Pt “seed” particles. The coercivity of FePt nanoparticles was measured at 300 K damped with decreasing particle sizes below 10 nm. High-density areal packing of Fe/Pt nanoparticles could be fabricated at 673 K on a slightly inclined NaCl(001) substrate with surface steps. These particles coalesced easily upon annealing along the <100> step edges. © 2003 American Institute of Physics.

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Journal of Applied Physics  (Volume:93 ,  Issue: 10 )