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Light-emitting diodes based on phosphorescent guest/polymeric host systems

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2 Author(s)
Vaeth, K.M. ; Imaging Materials and Media, Research and Development, and Electronic Imaging Products, Research and Development, Eastman Kodak Company, Rochester, New York 14650 ; Tang, C.W.

Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.1501748 

Fabrication of polymer light-emitting diodes based on emission from the phosphorescent molecule fac tris(2-phenylpyridine) iridium doped into a poly(vinyl carbazole) host are reported. Several spin-coating solvents were evaluated for deposition of the polymer layer; toluene and chlorobenzene were found to consistently produce device-quality films with sufficient incorporation of the dopant. For single-layered devices with Mg0.9Ag0.1 cathodes, the luminance efficiency at 20 mA/cm2 was measured to be 8.7 Cd/A for devices processed from chlorobenzene. This efficiency could be increased by over a factor of two with a trilayered device geometry consisting of the doped polymer layer, a hole-blocking layer, and electron transport layer. Further increases in efficiency, up to 30 Cd/A and 8.5% external quantum efficiency, were observed when a second dopant of 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole was added to the polymer emitter layer. © 2002 American Institute of Physics.

Published in:

Journal of Applied Physics  (Volume:92 ,  Issue: 7 )

Date of Publication:

Oct 2002

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