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Thermal properties of the nonlinear optical crystal zinc tris (thiourea) sulphate

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11 Author(s)
Kerkoc, P. ; Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, United Kingdom ; Venkataramanan, V. ; Lochran, S. ; Bailey, R.T.
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The heat capacity of crystalline zinc tris (thiourea) sulphate, has been measured in the range from 220 to 500 K by differential scanning calorimetry, and was found to obey the relationship Cp(T)=2.76×10-3 T+0.366 J g-1 K-1. Thermal expansion data have been measured in the range from 150 to 473 K. From these data, the principal thermal expansion coefficients were found to be α1=6.41×10-5 K-1, α2=4.52×10-5 K-1, and α3=-4.32×10-6 K-1. The thermal conductivity tensor of this orthorhombic crystal was calculated from values of the thermal diffusivity in the directions normal to the (100), (010), and (001) crystal planes by the laser flash method. The thermal conductivity coefficients at 295 K are k1=0.27 W m-1 K-1, k2=0.34 W m-1 K-1, and k3=0.54 W m-1 K-1. © 1996 American Institute of Physics.

Published in:

Journal of Applied Physics  (Volume:80 ,  Issue: 12 )

Date of Publication:

Dec 1996

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